N-(3,4-Dichlorophenyl)-2,4-dimethylbenzenesulfonamide
نویسندگان
چکیده
In the crystal structure of the title compound, C(14)H(13)Cl(2)NO(2)S, the configurations of the N-C bond with respect to the S=O bonds are trans and gauche. The mol-ecule is bent at the S atom with a C-SO(2)-NH-C torsion angle of -69.7 (2)°. The conformation of the N-H bond is syn to the 3-chloro group in the substituted aniline ring. The two benzene rings are tilted with respect to each other by 82.4 (1)°. The presence of N-H⋯O(S) hydrogen bonding packs the mol-ecules into supra-molecular chains along the b axis.
منابع مشابه
N-(2,3-Dichlorophenyl)-2,4-dimethylbenzenesulfonamide
In the title compound, C(14)H(13)Cl(2)NO(2)S, the dihedral angle between the two aromatic rings is 70.4 (1)°. The mol-ecular conformation is stabilized by an intra-molecular N-H⋯Cl hydrogen bond.
متن کاملN-(2,4-Dichlorophenyl)-2,4-dimethylbenzenesulfonamide
In the title compound, C(14)H(13)Cl(2)NO(2)S, the mol-ecule is bent at the S atom with an C-SO(2)-NH-C torsion angle of -69.9 (2)°. The dihedral angle between the sulfonyl and aniline benzene rings is 44.0 (1)°. The crystal structure features inversion dimers linked by pairs of N-H⋯O hydrogen bonds. An intra-molecular N-H⋯Cl hydrogen bond is also observed.
متن کاملN-(3,5-Dichlorophenyl)-2,4-dimethylbenzenesulfonamide
In the crystal structure of the title compound, C(14)H(13)Cl(2)NO(2)S, the conformation of the N-C bond in the C-SO(2)-NH-C segment has gauche torsions with respect to the S=O bonds. The mol-ecule is bent at the N atom, with an C-SO(2)-NH-C torsion angle of -54.9 (3)°. The two benzene rings are tilted relative to each other by 82.3 (2)°. The mol-ecules are linked into centrosymmetric R(2) (2)(8...
متن کاملN-(3,4-Dimethylphenyl)-2,4-dimethylbenzenesulfonamide
In the title compound, C(16)H(19)NO(2)S, the dihedral angle between the aromatic rings is 47.2 (2)°. The crystal structure features zigzag C(4) chains linked by N-H⋯O hydrogen bonds.
متن کامل2,4-Dichloro-N-(3,4-dichlorophenyl)benzenesulfonamide
In the crystal structure of the title compound, C(12)H(7)Cl(4)NO(2)S, the conformation of the N-H bond is syn to the meta-chloro residue in the aniline benzene ring. The two aromatic rings are tilted relative to each other by 68.9 (1)°. N-H⋯O hydrogen bonds connect the mol-ecules into centrosymmetric dimers.
متن کامل